Electronic Absorption, Emission, and Two-Photon Absorption Properties of Some Extended 2,4,6-Triphenyl-1,3,5-Triazines - Archive ouverte HAL Access content directly
Journal Articles Photochem Year : 2022

Electronic Absorption, Emission, and Two-Photon Absorption Properties of Some Extended 2,4,6-Triphenyl-1,3,5-Triazines

(1) , (1) , (2, 3) , (4) , (1) , (1) , (1)
1
2
3
4

Abstract

We report herein the linear optical properties of some extended 2,4,6-triphenyl-s-triazines of formula 2,4,6-[(1,4-C6H4)C≡C(4-C6H4X)]3-1,3,5-(C3H3N3) (3-X; X = NO2, CN, OMe, NMe2, NPh2) and related analogues 4 and 7-X (X = H, NPh2), before briefly discussing their two-photon absorption (2PA) cross-sections. Their 2PA performance is discussed in relation to 2PA values previously measured for closely related octupoles such as N,N′,N″-triphenylisocyanurates (1-X, 5, and 6-X) or 1,3,5-triphenylbenzenes (2-X). While s-triazines are usually much better two-photon absorbers in the near-IR range than these molecules, especially when functionalised by electron-releasing substituents at their periphery, they present a decreased transparency window in the visible range due to their red-shifted first 1PA peak, in particular when compared with corresponding isocyanurates analogues. In contrast, due to their significantly larger two-photon brilliancy, 2,4,6-triphenyl-s-triazines appear more promising than the latter for two-photon fluorescence bio-imaging purposes. Rationalisation of these unexpected outcomes is proposed based on DFT calculations.
Fichier principal
Vignette du fichier
Barnes-2022-Electronic Absorption, Emission, and Two-Photon.pdf (3.26 Mo) Télécharger le fichier
Vignette du fichier
Barnes_photochem-02-00023-s001.zip (2.39 Mo) Télécharger le fichier
Origin : Publisher files allowed on an open archive

Dates and versions

hal-03814572 , version 1 (14-10-2022)

Licence

Attribution - CC BY 4.0

Identifiers

Cite

Alison G Barnes, Nicolas Richy, Anissa Amar, Mireille Blanchard-Desce, Abdou Boucekkine, et al.. Electronic Absorption, Emission, and Two-Photon Absorption Properties of Some Extended 2,4,6-Triphenyl-1,3,5-Triazines. Photochem, 2022, 2 (2), pp.326-344. ⟨10.3390/photochem2020023⟩. ⟨hal-03814572⟩
26 View
2 Download

Altmetric

Share

Gmail Facebook Twitter LinkedIn More