An S = 12 semiquinoid radical-bridged Mn 6 wheel complex assembled from an asymmetric redox-active bridging ligand

Ie-Rang Jeon (1) , T. David Harris

1 Department of Chemistry [Northwestern University]

The asymmetric redox-active ligand 4,5-bis(pyridine-2-carboxamido)-1,2-catechol ( N,O LH 4 ) is synthesized and metalated to afford the S = 12 semiquinoid radical-bridged wheel complex [Mn II 6 ( N,O L 3− ˙) 6 ] 6− .

Domaines: Chimie

Ie-Rang Jeon, T. David Harris. An S = 12 semiquinoid radical-bridged Mn 6 wheel complex assembled from an asymmetric redox-active bridging ligand. Chemical Communications, 2016, 52 (5), pp.1006-1008. ⟨10.1039/C5CC08482B⟩. ⟨hal-03835640⟩