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Ruthenium-catalyzed ortho-C-H bond arylation reactions


The highly selective ruthenium-catalyzed ortho-C-H bond arylations have met a level of maturity that makes them an attractive tool to achieve unique organic transformations. By means of the manifold mechanisms operating in the presence of different arylating agents and reaction conditions, these methodologies have succeeded in reducing the wastes/steps toward the desired molecules as well as enlarging the chemical space by affording molecules impossible to obtain otherwise. The key achievements in this area are discussed in this article.
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hal-03891991 , version 1 (09-12-2022)



Christian Bruneau, Rafael Gramage-Doria. Ruthenium-catalyzed ortho-C-H bond arylation reactions. Handbook of CH-Functionalization, Wiley, 2022, ⟨10.1002/9783527834242.chf0032⟩. ⟨hal-03891991⟩
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