J. Frangioni, In vivo near-infrared fluorescence imaging, Current Opinion in Chemical Biology, vol.7, issue.5, pp.626-634, 2003.
DOI : 10.1016/j.cbpa.2003.08.007

H. S. Nalwa and S. Miyata, Nonlinear Optics of Organic Molecules and Polymers, Optical Engineering, vol.36, issue.9, 1996.
DOI : 10.1117/1.601490

P. Günter, Nonlinear optical effects and materials; Optical science, 2000.

M. G. Kuzyk and C. W. Dirk, Characterization techniques and tabulations for organic nonlinear optical materials, 1998.

R. Hellwarth and P. Christensen, Nonlinear optical microscopic examination of structure in polycrystalline ZnSe, Optics Communications, vol.12, issue.3, pp.318-322, 1974.
DOI : 10.1016/0030-4018(74)90024-8

R. W. Terhune, P. D. Maker, and C. M. Savage, Measurements of Nonlinear Light Scattering, Physical Review Letters, vol.14, issue.17, p.681, 1965.
DOI : 10.1103/PhysRevLett.14.681

K. Clays and A. Persoons, Hyper-Rayleigh scattering in solution, Physical Review Letters, vol.66, issue.23, pp.2980-2983, 1991.
DOI : 10.1103/PhysRevLett.66.2980

S. Brasselet and J. Zyss, Multipolar molecules and multipolar fields: probing and controlling the tensorial nature of nonlinear molecular media, Journal of the Optical Society of America B, vol.15, issue.1, pp.257-288, 1998.
DOI : 10.1364/JOSAB.15.000257

G. S. He, J. D. Bhawalkar, P. N. Prasad, and B. A. Reinhardt, Three-photon-absorption-induced fluorescence and optical limiting effects in an organic compound, Optics Letters, vol.20, issue.14, pp.1524-1526, 1995.
DOI : 10.1364/OL.20.001524

J. D. Bhawalkar, G. S. He, and P. N. Prasad, Nonlinear multiphoton processes in organic and polymeric materials, Reports on Progress in Physics, vol.59, issue.9, pp.1041-1070, 1996.
DOI : 10.1088/0034-4885/59/9/001

J. D. Bhawalkar, G. S. He, and P. N. Prasad, Three-photon induced upconverted fluorescence from an organic compound: application to optical power limiting, Optics Communications, vol.119, issue.5-6, pp.587-590, 1995.
DOI : 10.1016/0030-4018(95)00383-J

H. Meier, Conjugated Oligomers with Terminal Donor???Acceptor Substitution, Angewandte Chemie International Edition, vol.41, issue.2, pp.2482-2506, 2005.
DOI : 10.1002/anie.200461146

F. Meyers, S. R. Marder, B. M. Pierce, and J. L. Bredas, Electric Field Modulated Nonlinear Optical Properties of Donor-Acceptor Polyenes: Sum-Over-States Investigation of the Relationship between Molecular Polarizabilities (.alpha., .beta., and .gamma.) and Bond Length Alternation, Journal of the American Chemical Society, vol.116, issue.23, pp.10703-10714, 1994.
DOI : 10.1021/ja00102a040

I. Ledoux, J. Zyss, J. S. Siegel, J. Brienne, and J. M. Lehn, Second-harmonic generation from non-dipolar non-centrosymmetric aromatic charge-transfer molecules, Chemical Physics Letters, vol.172, issue.6, pp.440-444, 1990.
DOI : 10.1016/0009-2614(90)80135-Z

K. Sénéchal, O. Maury, H. Le-bozec, I. Ledoux, and J. Zyss, Zinc(II) as a Versatile Template for the Design of Dipolar and Octupolar NLO-phores, Journal of the American Chemical Society, vol.124, issue.17, pp.4560-4561, 2002.
DOI : 10.1021/ja025705a

T. Verbiest, S. Houbrechts, M. Kauranen, K. Clays, and A. Persoons, Second-order nonlinear optical materials: recent advances in chromophore design, Journal of Materials Chemistry, vol.7, issue.11, pp.2175-2189, 1997.
DOI : 10.1039/a703434b

K. Clays and B. Coe, Design Strategies versus Limiting Theory for Engineering Large Second-Order Nonlinear Optical Polarizabilities in Charged Organic Molecules, Chemistry of Materials, vol.15, issue.3, pp.642-648, 2003.
DOI : 10.1021/cm0212111

Y. Shi, C. Zhang, H. Zhang, J. H. Bechtel, L. R. Dalton et al., Low (Sub-1-Volt) Halfwave Voltage Polymeric Electro-optic Modulators Achieved by Controlling Chromophore Shape, Science, vol.288, issue.5463, pp.119-122, 2000.
DOI : 10.1126/science.288.5463.119

P. J. Campagnola, M. D. Wei, A. Lewis, and L. M. Loew, High-Resolution Nonlinear Optical Imaging of Live Cells by Second Harmonic Generation, Biophysical Journal, vol.77, issue.6, pp.3341-3349, 1999.
DOI : 10.1016/S0006-3495(99)77165-1

M. Albota, D. Beljonne, J. Bredas, J. E. Ehrlich, J. Fu et al., Design of Organic Molecules with Large Two-Photon Absorption Cross Sections, Science, vol.281, issue.5383, pp.1653-1656, 1998.
DOI : 10.1126/science.281.5383.1653

C. Martineau, G. Lemercier, C. Andraud, I. Wang, M. Bouriau et al., New initiator for two-photon absorption induced polymerization with a microlaser at 1.06 ??m, Synthetic Metals, vol.138, issue.1-2, pp.353-356, 2003.
DOI : 10.1016/S0379-6779(03)00111-5
URL : https://hal.archives-ouvertes.fr/hal-01321511

S. Kawata, H. B. Sun, T. Tanaka, and K. Takada, Finer features for functional microdevices, Nature, vol.24, issue.6848, pp.697-705, 2001.
DOI : 10.1038/35089130

I. Wang, M. Bouriau, P. L. Baldeck, C. Martineau, and C. Andraud, Three-dimensional microfabrication by two-photon-initiated polymerization with a low-cost microlaser, Optics Letters, vol.27, issue.15, pp.1348-1350, 2002.
DOI : 10.1364/OL.27.001348
URL : https://hal.archives-ouvertes.fr/hal-01321637

P. N. Prasad, Introduction to biophotonics, 2003.

W. Denk, J. H. Strickler, and W. W. Webb, Two-photon laser scanning fluorescence microscopy, Science, vol.248, issue.4951, pp.73-76, 1990.
DOI : 10.1126/science.2321027

K. Mansour, M. J. Soileau, and E. W. Van-stryland, Nonlinear optical properties of carbon-black suspensions (ink), Journal of the Optical Society of America B, vol.9, issue.7, pp.1100-1109, 1992.
DOI : 10.1364/JOSAB.9.001100

M. Cha, N. S. Sariciftci, A. J. Heeger, J. C. Hummelen, and F. Wudl, Enhanced nonlinear absorption and optical limiting in semiconducting polymer/methanofullerene charge transfer films, Applied Physics Letters, vol.67, issue.26, pp.3850-3852, 1995.
DOI : 10.1063/1.115294

C. W. Spangler, Recent development in the design of organic materials for optical power limiting, Journal of Materials Chemistry, vol.9, issue.9, pp.2013-2020, 1999.
DOI : 10.1039/a902802a

Y. P. Sun, J. E. Riggs, and B. Liu, Optical Limiting Properties of [60]Fullerene Derivatives, Chemistry of Materials, vol.9, issue.5, pp.1268-1272, 1997.
DOI : 10.1021/cm960650v

N. V. Kamanina, Y. M. Voronin, A. V. Varnaev, I. V. Bagrov, and A. P. Zhevlakov, Optical properties of the fullerene-doped polyimide in the near infrared, Synthetic Metals, vol.138, issue.1-2, pp.317-322, 2003.
DOI : 10.1016/S0379-6779(03)00031-6

E. Giorgetti, G. Toci, M. Vannini, and F. Giammanco, Multiphoton absorption of solutions of polydiacetylene polyDCHD-HS measured using ps Z-scan at 1064 and 1500 nm, Optics Communications, vol.217, issue.1-6, pp.431-439, 2003.
DOI : 10.1016/S0030-4018(03)01176-3

Q. Zheng, G. S. He, C. Lu, and P. N. Prasad, Synthesis, two- and three-photon absorption, and optical limiting properties of fluorene-containing ferrocene derivatives, Journal of Materials Chemistry, vol.40, issue.39, pp.3488-3493, 2005.
DOI : 10.1039/b508005c

Q. Zheng, G. S. He, A. Baev, and P. N. Prasad, Experimental and Quantum Chemical Studies of Cooperative Enhancement of Three-Photon Absorption, Optical Limiting, and Stabilization Behaviors in Multibranched and Dendritic Structures, The Journal of Physical Chemistry B, vol.110, issue.30, pp.14604-14610, 2006.
DOI : 10.1021/jp0617874

G. S. He, K. Yong, Q. Zheng, Y. Sahoo, A. Baev et al., Multi-photon excitation properties of CdSe quantum dots solutions and optical limiting behavior in infrared range, Optics Express, vol.15, issue.20, pp.12818-12833, 2007.
DOI : 10.1364/OE.15.012818

M. Green, Semiconductor Quantum Dots as Biological Imaging Agents, Angewandte Chemie International Edition, vol.43, issue.32, pp.4129-4131, 2004.
DOI : 10.1002/anie.200301758

G. S. He, Q. Zheng, K. Yong, A. I. Ryasnyanskiy, and P. N. Prasad, Two-photon absorption based optical limiting and stabilization by using a CdTe quantum dot solution excited at optical communication wavelength of ???1300nm, Applied Physics Letters, vol.90, issue.18, pp.181108-181111, 2007.
DOI : 10.1063/1.2734904

R. L. Allen, Color Chemistry (Studies in Modern Chemistry), 1971.

J. Griffiths, Color and Constitution of Organic Molecules, 1976.

J. Fabian, H. Nakazumi, and M. Matsuoka, Near-infrared absorbing dyes, Chemical Reviews, vol.92, issue.6, pp.1197-1226, 1992.
DOI : 10.1021/cr00014a003

R. Hoffmann, Solids and Surfaces: A Chemsit's view on Bonding in Extended Strcuture, 1988.

J. Roncali, Synthetic Principles for Bandgap Control in Linear ??-Conjugated Systems, Chemical Reviews, vol.97, issue.1, pp.173-206, 1997.
DOI : 10.1021/cr950257t

T. Baumgartner and R. Réau, , 4681???4727. Published on the Web November 8, 2006.), Chemical Reviews, vol.107, issue.1, pp.303-303, 2007.
DOI : 10.1021/cr068047b

Y. Avlasevich and K. Mullen, An Efficient Synthesis of Quaterrylenedicarboximide NIR Dyes, The Journal of Organic Chemistry, vol.72, issue.26, pp.10243-10246, 2007.
DOI : 10.1021/jo702019p

S. Dähne and R. Radeglia, Revision der Lewis-Calvin-Regel zur charakterisierung vinyloger. Polyen- und polymethin??hnlicher verbindungen, Tetrahedron, vol.27, issue.15, pp.3673-3693, 1971.
DOI : 10.1016/S0040-4020(01)97778-6

A. Mishra, R. K. Behera, P. K. Behera, B. K. Mishra, and G. B. Behera, Cyanines during the 1990s:?? A Review, Chemical Reviews, vol.100, issue.6, pp.1973-2011, 2000.
DOI : 10.1021/cr990402t

K. Jyothish, R. R. Avirah, and D. Ramaiah, Synthesis of New Cholesterol- and Sugar-Anchored Squaraine Dyes:??? Further Evidence of How Electronic Factors Influence Dye Formation, Organic Letters, vol.8, issue.1, pp.111-114, 2006.
DOI : 10.1021/ol052639j

K. Takechi, P. V. Kamat, R. R. Avirah, K. Jyothish, and D. Ramaiah, Harvesting Infrared Photons with Croconate Dyes, Chemistry of Materials, vol.20, issue.1, pp.265-272, 2008.
DOI : 10.1021/cm7018668

K. Maruszewski, M. Jasiorski, and W. Strek, Spectroscopic behavior of 1,1???-diethyl-2,2???-dicarbocyanine iodide in ethanol/water solutions with high ionic strength, Journal of Molecular Structure, vol.610, issue.1-3, pp.187-190, 2002.
DOI : 10.1016/S0022-2860(02)00049-2

G. Ulrich, R. Ziessel, and A. Harriman, The Chemistry of Fluorescent Bodipy Dyes: Versatility Unsurpassed, Angewandte Chemie International Edition, vol.107, issue.7, pp.1184-1201, 2008.
DOI : 10.1002/anie.200702070

A. Loudet and K. Burgess, BODIPY Dyes and Their Derivatives:?? Syntheses and Spectroscopic Properties, Chemical Reviews, vol.107, issue.11, pp.4891-4932, 2007.
DOI : 10.1021/cr078381n

R. Ziessel, G. Ulrich, and A. Harriman, The chemistry of Bodipy: A new El Dorado for fluorescence tools, New Journal of Chemistry, vol.13, issue.4, pp.496-501, 2007.
DOI : 10.1039/b617972j

W. J. Yang, D. Y. Kim, M. Jeong, H. M. Kim, Y. K. Lee et al., Two-Photon Absorption Properties of 2,6-Bis(styryl)anthracene Derivatives: Effects of Donor-Acceptor Substituents and the ?? Center, Chemistry - A European Journal, vol.13, issue.14, pp.4191-4198, 2005.
DOI : 10.1002/chem.200401134

J. M. Hales, S. Zheng, S. Barlow, S. R. Marder, and J. W. Perry, Bisdioxaborine Polymethines with Large Third-Order Nonlinearities for All-Optical Signal Processing, Journal of the American Chemical Society, vol.128, issue.35, pp.11362-11363, 2006.
DOI : 10.1021/ja063535m

J. Fu, L. A. Padilha, D. J. Hagan, E. W. Van-stryland, O. V. Przhonska et al., Molecular structure???two-photon absorption property relations in polymethine dyes, Journal of the Optical Society of America B, vol.24, issue.1, pp.56-66, 2007.
DOI : 10.1364/JOSAB.24.000056

M. O. Senge, M. Fazekas, E. G. Notaras, M. Zawadzka, W. J. Blau et al., Nonlinear Optical Properties of Porphyrins, Advanced Materials, vol.127, issue.19, pp.2737-2774, 2007.
DOI : 10.1002/adma.200601850

T. C. Wen, L. C. Hwang, W. Y. Lin, C. H. Chen, and C. H. Wu, Nonlinear absorption of light: two-photon absorption and optical saturation in metalloporphyrin-doped boric acid glass, Chemical Physics, vol.286, issue.2-3, pp.293-302, 2003.
DOI : 10.1016/S0301-0104(02)00958-8

J. Humphrey and D. Kuciauskas, Charge-Transfer States Determine Iron Porphyrin Film Third-Order Nonlinear Optical Properties in the near-IR Spectral Region, The Journal of Physical Chemistry B, vol.108, issue.32, pp.12016-12023, 2004.
DOI : 10.1021/jp0485643

K. Kurotobi, K. S. Kim, S. B. Noh, D. Kim, and A. Osuka, A Quadruply Azulene-Fused Porphyrin with Intense Near-IR Absorption and a Large Two-Photon Absorption Cross Section, Angewandte Chemie International Edition, vol.46, issue.24, pp.3944-3947, 2006.
DOI : 10.1002/anie.200600892

Y. Luo, O. Rubio-pons, J. Guo, and H. Agren, Charge-transfer Zn-porphyrin derivatives with very large two-photon absorption cross sections at 1.3???1.5 ??m fundamental wavelengths, The Journal of Chemical Physics, vol.122, issue.9, pp.96101-96103, 2005.
DOI : 10.1063/1.1858864

S. Mori, K. S. Kim, Z. S. Yoon, S. B. Noh, D. Kim et al., Peripheral Fabrications of a Bis-Gold(III) Complex of [26]Hexaphyrin(1.1.1.1.1.1) and Aromatic versus Antiaromatic Effect on Two-Photon Absorption Cross Section, Journal of the American Chemical Society, vol.129, issue.37, pp.11344-11345, 2007.
DOI : 10.1021/ja0744908

M. Drobizhev, N. S. Makarov, A. Rebane, G. Delatorre, and T. Torres, Strong Two-Photon Absorption in Push???Pull Phthalocyanines:??? Role of Resonance Enhancement and Permanent Dipole Moment Change upon Excitation, The Journal of Physical Chemistry C, vol.112, issue.3, pp.848-859, 2008.
DOI : 10.1021/jp073318n

E. W. Van-stryland, M. A. Woodall, H. Vanherzeele, and M. Soileau, Energy band-gap dependence of two-photon absorption, Optics Letters, vol.10, issue.10, pp.490-492, 1985.
DOI : 10.1364/OL.10.000490

S. A. Hilderbrand, K. A. Kelly, R. Weissleder, and C. H. Tung, Monofunctional Near-Infrared Fluorochromes for Imaging Applications, Bioconjugate Chemistry, vol.16, issue.5, pp.1275-1281, 2005.
DOI : 10.1021/bc0501799

W. M. Leevy, S. T. Gammon, H. Jiang, J. R. Johnson, D. J. Maxwell et al., Optical Imaging of Bacterial Infection in Living Mice Using a Fluorescent Near-Infrared Molecular Probe, Journal of the American Chemical Society, vol.128, issue.51, pp.16476-16477, 2006.
DOI : 10.1021/ja0665592

R. C. Benson and H. A. Kues, Absorption and fluorescence properties of cyanine dyes, Journal of Chemical & Engineering Data, vol.22, issue.4, pp.379-383, 1977.
DOI : 10.1021/je60075a020

G. A. Reynolds and K. H. Drexhage, Stable heptamethine pyrylium dyes that absorb in the infrared, The Journal of Organic Chemistry, vol.42, issue.5, pp.885-888, 1977.
DOI : 10.1021/jo00425a027

L. M. Tolbert and X. Zhao, Beyond the Cyanine Limit:?? Peierls Distortion and Symmetry Collapse in a Polymethine Dye, Journal of the American Chemical Society, vol.119, issue.14, pp.3253-3258, 1997.
DOI : 10.1021/ja9626953

R. S. Lepkowicz, O. V. Przhonska, J. M. Hales, J. Fu, D. J. Hagan et al., Nature of the electronic transitions in thiacarbocyanines with a long polymethine chain, Chemical Physics, vol.305, issue.1-3, pp.259-270, 2004.
DOI : 10.1016/j.chemphys.2004.06.063

A. D. Kachkovskii, The Solitonic Nature of the Electronic Structure of the Ions of Linear Conjugated Systems, Theoretical and Experimental Chemistry, vol.103, issue.3, pp.139-164, 2005.
DOI : 10.1007/s11237-005-0034-8

M. Guillaume, V. Liégeois, B. Champagne, and F. Zutterman, Time-dependent density functional theory investigation of the absorption and emission spectra of a cyanine dye, Chemical Physics Letters, vol.446, issue.1-3, pp.165-169, 2007.
DOI : 10.1016/j.cplett.2007.07.105

B. Champagne, M. Guillaume, and F. Zutterman, TDDFT investigation of the optical properties of cyanine dyes, Chemical Physics Letters, vol.425, issue.1-3, pp.105-109, 2006.
DOI : 10.1016/j.cplett.2006.05.009

N. Narayanan and G. Patonay, A New Method for the Synthesis of Heptamethine Cyanine Dyes: Synthesis of New Near-Infrared Fluorescent Labels, The Journal of Organic Chemistry, vol.60, issue.8, pp.2391-2395, 1995.
DOI : 10.1021/jo00113a018

X. Peng, F. Song, E. Lu, Y. Wang, W. Zhou et al., Heptamethine Cyanine Dyes with a Large Stokes Shift and Strong Fluorescence:?? A Paradigm for Excited-State Intramolecular Charge Transfer, Journal of the American Chemical Society, vol.127, issue.12, pp.4170-4171, 2005.
DOI : 10.1021/ja043413z

K. Kiyose, H. Kojima, Y. Urano, and T. Nagano, Development of a Ratiometric Fluorescent Zinc Ion Probe in Near-Infrared Region, Based on Tricarbocyanine Chromophore, Journal of the American Chemical Society, vol.128, issue.20, pp.6548-6549, 2006.
DOI : 10.1021/ja060399c

M. Zhu, M. Yuan, X. Liu, J. Xu, J. Lv et al., Visible Near-Infrared Chemosensor for Mercury Ion, Organic Letters, vol.10, issue.7, pp.1481-1484, 2008.
DOI : 10.1021/ol800197t

N. A. Koska, S. R. Wilson, and G. B. Schuster, Penetrated ion pairs: structure and properties of (N,N'-dimethyl)dimethylindocarbocyanine tetrakis(phenylethynyl)borate in solution and in the solid state, Journal of the American Chemical Society, vol.115, issue.24, pp.11628-11629, 1993.
DOI : 10.1021/ja00077a084

J. Lacour, A. Londez, C. Goujon-ginglinger, V. Buss, and G. Bernardinelli, -Symmetric Hexacoordinated Phosphate Anion, Organic Letters, vol.2, issue.26, pp.4185-4188, 2000.
DOI : 10.1021/ol006731l
URL : https://hal.archives-ouvertes.fr/hal-00857428

H. Yao, T. Isohashi, and K. Kimura, Electrolyte-Induced Mesoscopic Aggregation of Thiacarbocyanine Dye in Aqueous Solution:?? Counterion Size Specificity, The Journal of Physical Chemistry B, vol.111, issue.25, pp.7176-7183, 2007.
DOI : 10.1021/jp070520h

R. S. Lepkowicz, C. M. Cirloganu, J. Fu, O. V. Przhonska, D. J. Hagan et al., Femtosecond-to-nanosecond nonlinear spectroscopy of polymethine molecules, Journal of the Optical Society of America B, vol.22, issue.12, pp.2664-2684, 2005.
DOI : 10.1364/JOSAB.22.002664

S. S. Ramos, P. F. Santos, L. V. Reis, and P. Almeida, Some new symmetric rigidified triheterocyclic heptamethinecyanine dyes absorbing in the near infrared, Dyes and Pigments, vol.53, issue.2, pp.143-152, 2002.
DOI : 10.1016/S0143-7208(02)00003-7

F. Song, X. Peng, E. Lu, R. Zhang, X. Chen et al., Syntheses, spectral properties and photostabilities of novel water-soluble near-infrared cyanine dyes, Journal of Photochemistry and Photobiology A: Chemistry, vol.168, issue.1-2, pp.53-57, 2004.
DOI : 10.1016/j.jphotochem.2004.05.012

H. Johannes, W. Grahn, A. Reisner, and P. G. Jones, Ethynylated, vinylated, and hetarylated indodicarbocyanines by palladium-catalyzed cross-coupling reactions, Tetrahedron Letters, vol.36, issue.40, pp.7225-7228, 1995.
DOI : 10.1016/0040-4039(95)01535-P

H. Lee, J. C. Mason, and S. Achilefu, Heptamethine Cyanine Dyes with a Robust C???C Bond at the Central Position of the Chromophore, The Journal of Organic Chemistry, vol.71, issue.20, pp.7862-7865, 2006.
DOI : 10.1021/jo061284u

Y. L. Slominsky, A. D. Kachkovski, S. V. Popov, L. A. Nechitailo, and N. Ignatiev, Anionic polymethine dyes containing a vinylene bridge, Dyes and Pigments, vol.15, issue.4, pp.247-254, 1991.
DOI : 10.1016/0143-7208(91)80009-X

A. V. Kulinich, N. A. Derevyanko, and A. A. Ishchenko, Electronic structure and solvatochromism of merocyanines based on N,N-diethylthiobarbituric acid, Journal of Photochemistry and Photobiology A: Chemistry, vol.188, issue.2-3, pp.207-217, 2007.
DOI : 10.1016/j.jphotochem.2006.12.014

A. S. Tatikolov and S. M. Costa, Medium effects on the isomerization of an anionic polymethine dye, Chemical Physics Letters, vol.440, issue.1-3, pp.73-78, 2007.
DOI : 10.1016/j.cplett.2007.04.003

A. J. Kay, A. D. Woolhouse, Y. Zhao, and K. Clays, Synthesis and linear/nonlinear optical properties of a new class of ???RHS??? NLO chromophore, J. Mater. Chem., vol.25, issue.8, pp.1321-1330, 2004.
DOI : 10.1039/B315274J

G. Melikian, F. P. Rouessac, and C. Alexandre, Synthesis of Substituted Dicyanomethylendihydrofurans, Synthetic Communications, vol.47, issue.19, pp.3045-3051, 1995.
DOI : 10.1002/jlac.19093640204

T. Sakata, D. K. Jackson, S. Mao, and G. Marriott, Optically Switchable Chelates:?? Optical Control and Sensing of Metal Ions, The Journal of Organic Chemistry, vol.73, issue.1, pp.227-233, 2008.
DOI : 10.1021/jo7019898

H. Ma and A. K. Jen, Functional Dendrimers for Nonlinear Optics, Advanced Materials, vol.13, issue.15, pp.1201-1205, 2001.
DOI : 10.1002/1521-4095(200108)13:15<1201::AID-ADMA1201>3.0.CO;2-F

R. Vestberg, A. Nystrom, M. Lindgren, E. Malmstrom, and A. Hult, Porphyrin-Cored 2,2-Bis(methylol)propionic Acid Dendrimers, Chemistry of Materials, vol.16, issue.14, pp.2794-2804, 2004.
DOI : 10.1021/cm035354e

V. V. Rostovtsev, L. G. Green, V. V. Fokin, and B. K. Sharpless, A Stepwise Huisgen Cycloaddition Process: Copper(I)-Catalyzed Regioselective ???Ligation??? of Azides and Terminal Alkynes, Angewandte Chemie International Edition, vol.20, issue.14, pp.2596-2599, 2002.
DOI : 10.1002/1521-3773(20020715)41:14<2596::AID-ANIE2596>3.0.CO;2-4

C. W. Tornoe, C. Christensen, and M. Meldal, Peptidotriazoles on Solid Phase:?? [1,2,3]-Triazoles by Regiospecific Copper(I)-Catalyzed 1,3-Dipolar Cycloadditions of Terminal Alkynes to Azides, The Journal of Organic Chemistry, vol.67, issue.9, pp.3057-3064, 2002.
DOI : 10.1021/jo011148j

H. C. Kolb, M. G. Finn, and B. K. Sharpless, Click Chemistry: Diverse Chemical Function from a Few Good Reactions, Angewandte Chemie International Edition, vol.36, issue.6, pp.2004-2021, 2001.
DOI : 10.1002/1521-3773(20010601)40:11<2004::AID-ANIE2004>3.0.CO;2-5

C. J. Hawker, V. Fokin, M. G. Finn, and B. K. Sharpless, Bringing Efficiency to Materials Synthesis: The Philosophy of Click Chemistry, Australian Journal of Chemistry, vol.60, issue.6, pp.381-383, 2007.
DOI : 10.1071/CH07107

T. W. Greene, Protective groups in organic synthesis, 1981.
DOI : 10.1002/0471220574

K. Kamada, K. Matsunaga, A. Yoshino, and K. Ohta, Two-photon-absorption-induced accumulated thermal effect on femtosecond Z-scan experiments studied with time-resolved thermal-lens spectrometry and its simulation, Journal of the Optical Society of America B, vol.20, issue.3, pp.529-537, 2003.
DOI : 10.1364/JOSAB.20.000529

K. Ogawa, A. Ohashi, Y. Kobuke, K. Kamada, and K. Ohta, Strong Two-Photon Absorption of Self-Assembled Butadiyne-Linked Bisporphyrin, Journal of the American Chemical Society, vol.125, issue.44, pp.13356-13357, 2003.
DOI : 10.1021/ja035056i

J. March, Advanced organic chemistry, 1992.

J. Lacour, C. Ginglinger, C. Grivet, and G. Bernardinelli, Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate(V) Ion, Angewandte Chemie International Edition in English, vol.36, issue.6, pp.608-610, 1997.
DOI : 10.1002/anie.199706081

C. Xu and W. W. Webb, Measurement of two-photon excitation cross sections of molecular fluorophores with data from 690 to 1050 nm, Journal of the Optical Society of America B, vol.13, issue.3, p.481, 1996.
DOI : 10.1364/JOSAB.13.000481

G. H. Springer and D. A. Higgins, Multiphoton-Excited Fluorescence Imaging and Photochemical Modification of Dye-Doped Polystyrene Microsphere Arrays, Chemistry of Materials, vol.12, issue.5, pp.1372-1377, 2000.
DOI : 10.1021/cm9907256

L. Porrès, O. Mongin, and M. Blanchard-desce, Synthesis, fluorescence and two-photon absorption properties of multichromophoric boron-dipyrromethene fluorophores for two-photon-excited fluorescence applications, Tetrahedron Letters, vol.47, issue.12, pp.1913-1917, 2006.
DOI : 10.1016/j.tetlet.2006.01.087

S. O. Mcdonnell and D. F. Shea, ???Azadipyrromethenes, Organic Letters, vol.8, issue.16, pp.3493-3496, 2006.
DOI : 10.1021/ol061171x

M. J. Hall, S. O. Mcdonnell, J. Killoran, and D. F. Shea, A Modular Synthesis of Unsymmetrical Tetraarylazadipyrromethenes, The Journal of Organic Chemistry, vol.70, issue.14, pp.5571-5578, 2005.
DOI : 10.1021/jo050696k

A. Loudet, R. Bandichhor, L. Wu, and K. Burgess, Functionalized BF2 chelated azadipyrromethene dyes, Tetrahedron, vol.64, issue.17, pp.3642-3654, 2008.
DOI : 10.1016/j.tet.2008.01.117

A. Coskun, M. D. Yilmaz, and E. U. Akkaya, Bis(2-pyridyl)-Substituted Boratriazaindacene as an NIR-Emitting Chemosensor for Hg(II), Organic Letters, vol.9, issue.4, pp.607-609, 2007.
DOI : 10.1021/ol062867t

W. Zhao and E. M. Carreira, Conformationally Restricted Aza-Bodipy: A Highly Fluorescent, Stable, Near-Infrared-Absorbing Dye, Angewandte Chemie International Edition, vol.105, issue.11, pp.1677-1679, 2005.
DOI : 10.1002/anie.200461868

W. Zhao and E. M. Carreira, Conformationally Restricted Aza-BODIPY: Highly Fluorescent, Stable Near-Infrared Absorbing Dyes, Chemistry - A European Journal, vol.76, issue.27, pp.7254-7263, 2006.
DOI : 10.1002/chem.200600527

T. S. Teets, D. V. Partyka, A. J. Esswein, J. B. Updegraff, M. Zeller et al., Copper, Silver, and Gold, Inorganic Chemistry, vol.46, issue.16, pp.6218-6220, 2007.
DOI : 10.1021/ic700776t

M. J. Hall, L. T. Allen, and D. F. Shea, PET modulated fluorescent sensing from the BF2 chelated azadipyrromethene platform, Organic & Biomolecular Chemistry, vol.94, issue.5, pp.776-780, 2006.
DOI : 10.1039/b514788c

A. Coskun and E. U. Akkaya, Signal Ratio Amplification via Modulation of Resonance Energy Transfer:?? Proof of Principle in an Emission Ratiometric Hg(II) Sensor, Journal of the American Chemical Society, vol.128, issue.45, pp.14474-14475, 2006.
DOI : 10.1021/ja066144g

A. P. De-silva, H. Q. Gunaratne, T. Gunnlaugsson, A. J. Huxley, C. P. Mccoy et al., Signaling Recognition Events with Fluorescent Sensors and Switches, Chemical Reviews, vol.97, issue.5, pp.1515-1566, 1997.
DOI : 10.1021/cr960386p

M. Malkoch, E. Malmström, and A. Hult, Rapid and Efficient Synthesis of Aliphatic Ester Dendrons and Dendrimers, Macromolecules, vol.35, issue.22, pp.8307-8314, 2002.
DOI : 10.1021/ma0205360

. Ml, Diethylamine (12.5 mL, 120 mmol, 5 eq.) and nitromethane (6.5 mL, 120 mmol, 5 eq.) are then added. The solution is refluxed overnight. After cooling down to RT, the solution is quenched with a diluted aqueous solution of hydrochloric acid. The solution is extracted with ethyl acetate

S. O. Mcdonnell and D. F. Shea, ???Azadipyrromethenes, Organic Letters, vol.8, issue.16, pp.3493-3496, 2006.
DOI : 10.1021/ol061171x

K. Liu, H. Cui, J. Nie, K. Dong, X. Li et al., Highly Enantioselective Michael Addition of Aromatic Ketones to Nitroolefins Promoted by Chiral Bifunctional Primary Amine-thiourea Catalysts Based on Saccharides, Organic Letters, vol.9, issue.5, pp.923-925, 2007.
DOI : 10.1021/ol0701666

2. Hz, RMN 13 C (50.32 MHz, CDCl 3 ): ? 39

4. Hz, 99 (d, 3 J = 7 Hz, 4H) 13 C NMR (50.32 MHz): 115

4. Hz, 13 C NMR (50.32 MHz, CDCl 3 ): 118

P. Bouit, G. Wetzel, G. Berginc, B. Loiseaux, P. Toupet et al., Near IR Nonlinear Absorbing Chromophores with Optical Limiting Properties at Telecommunication Wavelengths, Chemistry of Materials, vol.19, issue.22, pp.5325-5335, 2007.
DOI : 10.1021/cm071557h
URL : https://hal.archives-ouvertes.fr/hal-01320790

P. Bouit, . Berginc, P. Toupet, K. Feneyrou, O. Kamada et al., accepté. Two photon absorption properties of functionalized-BODIPY dyes in the near infrared spectral range up to telecommunication wavelengths, Adv. Mat