Tetrathiafulvalene-Based Magnets of Lanthanides

Abstract : Tetrathiafulvalene (TTF)-based ligands and lanthanide ions have been intensively used for their electronic conductivity and optical properties, respectively. Their combination leads to a new class of coordination compounds that are able to display single-molecule magnet (SMM) behavior. Magnetic bistability resulting of such behavior could find potential applications in high-density data storage and quantum computing. In this chapter, a library of TTF-based magnets containing lanthanide ions is presented. Among this series, the influence of the coordination sphere and intra- and intermolecular interactions such as exchange, dipolar, supramolecular, and hyperfine interactions is probed through molecular engineering, magnetic dilutions, and isotopic enrichment.
Type de document :
Chapitre d'ouvrage
Topics in Organometallic Chemistry, Springer, 2018
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01940620
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Soumis le : vendredi 14 décembre 2018 - 15:52:05
Dernière modification le : jeudi 7 février 2019 - 16:55:23
Document(s) archivé(s) le : vendredi 15 mars 2019 - 13:08:21

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  • HAL Id : hal-01940620, version 1

Citation

Olivier Cador, Fabrice Pointillart. Tetrathiafulvalene-Based Magnets of Lanthanides. Topics in Organometallic Chemistry, Springer, 2018. 〈hal-01940620〉

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