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Journal articles
Synthesis, reactivity, and some photochemistry of ortho-N,N-dimethylaminomethyl substituted aryl and ferrocenyl pentamethylcyclopentadienyl dicarbonyl iron complexes
Abstract : Ortho-lithiated N,N-dimethylaminomethyl ferrocene and benzyldimethylamine react with Cp*Fe(CO)2I to give the new complexes ((Cp*Fe(CO)2)-2-(CH2NMe2)C5H3)Fe(Cp) and Cp*Fe(CO)2-C6H4(o-CH2NMe2). Access to a wide variety of alkoxy-substituted complexes ((Cp*Fe(CO)2)-2-(CH2OR)C5H3)Fe(Cp) can be easily achieved by tandem quaternization/alcoholysis of ((Cp*Fe(CO)2)-2-(CH2NMe2)C5H3)Fe(Cp). Preliminary results show that chelated complexes can be obtained by displacement of one of the carbonyl ligands by photolysis. Crystal structures of ((Cp*Fe(CO)2)-2-(CH2NMe2)C5H3)Fe(Cp), ((Cp*Fe(CO)2)-2-(CH2OR)C5H3)Fe(Cp) (R = Ph, Bz, CHPh2 and d-menthyl) and [Cp*Fe(CO)2-C6H4(o-CH2NMe2)][I] are reported.
Cited literature [34 references]
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00840900
Contributor : Laurent Jonchère <>
Submitted on : Wednesday, July 3, 2013 - 2:41:43 PM
Last modification on : Wednesday, October 14, 2020 - 3:42:15 AM
Long-term archiving on: : Friday, October 4, 2013 - 4:10:46 AM
Contributor : Laurent Jonchère <>
Submitted on : Wednesday, July 3, 2013 - 2:41:43 PM
Last modification on : Wednesday, October 14, 2020 - 3:42:15 AM
Long-term archiving on: : Friday, October 4, 2013 - 4:10:46 AM
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