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Journal articles
Imidazolidinium ferrate complexes: Synthesis and catalytic properties
Abstract : The new well-defined and air stable anionic iron complexes bearing an imidazolidinium ligand (2a–d) have been synthesized and characterized by elemental analysis and single-crystal X-ray diffraction studies. Starting from FeBr2, [imidazolidinium][FeBr4] complexes 2a and 2b were prepared. The reaction of imidazolidinium chlorides with Fe(OAc)2, followed by a recrystallization in the air led to bis(imidazolidinium) μ-oxido-bis[trichloroferrate(III)] complexes 2c and 2d. The catalytic activity of these novel complexes has been evaluated in the cross-coupling reactions of alkyl halides with Grignard reagents.
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01121095
Contributor : Béatrice Mahi <>
Submitted on : Friday, February 27, 2015 - 1:48:12 PM
Last modification on : Thursday, March 5, 2020 - 2:04:54 PM
Contributor : Béatrice Mahi <>
Submitted on : Friday, February 27, 2015 - 1:48:12 PM
Last modification on : Thursday, March 5, 2020 - 2:04:54 PM