Skip to Main content Skip to Navigation
Book sections

Organizing Radical Species in the Solid State with Halogen Bonding.

Abstract : The electronic properties (conductivity, magnetism) of radical systems in the solid state essentially depend on (1) the extent of delocalization of the spin density in the molecule and (2) the intermolecular interactions between radicals. The halogen bond has proven very efficient in engineering such magnetic or conducting structures and recent advances along these lines are reviewed here. Three situations are considered: (1) halogenated radical species acting as halogen bond donors, as found in iodotetrathiafulvalene-based chiral conductors or bilayer systems, and in spin crossover (SCO) complexes with halogenated ligands, (2) radical species acting as halogen bond acceptors, such as neutral nitronyl species or anionic, mixed-valence dithiolene complexes, interacting with closed-shell halogen bond donors (iodoperfluoro alkanes and arenes, iodo- or bromo-pyridinium cations), and, finally, (3) charge transfer salts where both halogen bond donor and acceptor are radical species.
Document type :
Book sections
Complete list of metadatas

Cited literature [83 references]  Display  Hide  Download

https://hal-univ-rennes1.archives-ouvertes.fr/hal-01141728
Contributor : Valérie Nieps <>
Submitted on : Tuesday, May 26, 2015 - 2:41:03 PM
Last modification on : Friday, July 10, 2020 - 4:11:55 PM
Long-term archiving on: : Tuesday, September 15, 2015 - 6:54:22 AM

File

Organizing Radical Species in ...
Files produced by the author(s)

Identifiers

Citation

Marc Fourmigué, Julien Lieffrig. Organizing Radical Species in the Solid State with Halogen Bonding.. Topics in Current Chemistry, Springer, pp.91-113, 2015, ⟨10.1007/128_2014_604⟩. ⟨hal-01141728⟩

Share

Metrics

Record views

421

Files downloads

281