Binuclear Cu(II) coordination complex involving cis-tetrathiafulvalene-bis-amido-2-pyridine-N-oxide as bi-anionic ligand: a robust molecular precursor toward magnetic conducting materials.

Fabrice Pointillart (1) , Thomas Cauchy (1) , Yann Le Gal (1) , Stéphane Golhen (1) , Olivier Cador (1) , Lahcene Ouahab (1)

1 ISCR - Institut des Sciences Chimiques de Rennes

Synthesis, electrochem., x-ray structure, exptl. and TD-DFT calcns. of photophys. properties were explored for the [Cu2(Cis-TTF-bis-CON-2-Py-N-oxide)2] binuclear coordination complex involving cis-tetrathiafulvalene-bis-amido-2-pyridine-N-oxide as a bi-anionic ligand. [on SciFinder(R)]

Keywords: binuclear copper tetrathiafulvalenebisamidopyridineoxide complex prepn crystal structure cyclic voltammetry

Domains: Chemical Sciences; Organic chemistry

Fabrice Pointillart, Thomas Cauchy, Yann Le Gal, Stéphane Golhen, Olivier Cador, et al.. Binuclear Cu(II) coordination complex involving cis-tetrathiafulvalene-bis-amido-2-pyridine-N-oxide as bi-anionic ligand: a robust molecular precursor toward magnetic conducting materials.. Chemical Communications, 2010, 46, pp.4947--4949. ⟨10.1039/c0cc00672f⟩. ⟨hal-01151347⟩