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Binuclear gadolinium(III) coordination complex based on bridging tetrathiafulvalenecarboxylate radical cations.

Fabrice Pointillart 1 Yann Le Gal 1 Stéphane Golhen 1 Olivier Cador 1 Lahcene Ouahab 1
1 ISCR - Institut des Sciences Chimiques de Rennes
Abstract : X-Ray structure, photophys. and magnetic properties have been explored for the binuclear gadolinium(III) coordination complex based on bridging tetrathiafulvalenecarboxylate radical cations [Gd(hfac)3(μ-TTFCO2)]2 (hfac = hexafluoroacetylacetonate).
Keywords : antiferromagnetic exchange gadolinium thiafulvalenecarboxylato fluoroacetylacetonato dinuclear complex charge transfer spectra gadolinium thiafulvalenecarboxylato fluoroacetylacetonato dinuclear complex crystal structure gadolinium thiafulvalenecarboxylato fluoroacetylacetonato dinuclear complex gadolinium thiafulvalenecarboxylato fluoroacetylacetonato dinuclear complex prepn structure magnetic property gadolinium thiafulvalenecarboxylato fluoroacetylacetonato dinuclear complex
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01151563
Contributor : Laurent Jonchère <>
Submitted on : Wednesday, May 13, 2015 - 10:21:46 AM
Last modification on : Thursday, March 5, 2020 - 2:07:16 PM

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UNIV-RENNES1 | SCR_MACSE | ISCR | CNRS | ISCR-OMC | INC-CNRS | UR1-UFR-SPM | UNIV-RENNES | INSA-GROUPE

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Fabrice Pointillart, Yann Le Gal, Stéphane Golhen, Olivier Cador, Lahcene Ouahab. Binuclear gadolinium(III) coordination complex based on bridging tetrathiafulvalenecarboxylate radical cations.. Chemical Communications, Royal Society of Chemistry, 2009, pp.3777--3779. ⟨10.1039/b901932d⟩. ⟨hal-01151563⟩

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