Binuclear gadolinium(III) coordination complex based on bridging tetrathiafulvalenecarboxylate radical cations.

Fabrice Pointillart (1) , Yann Le Gal (1) , Stéphane Golhen (1) , Olivier Cador (1) , Lahcene Ouahab (1)

1 ISCR - Institut des Sciences Chimiques de Rennes

X-Ray structure, photophys. and magnetic properties have been explored for the binuclear gadolinium(III) coordination complex based on bridging tetrathiafulvalenecarboxylate radical cations [Gd(hfac)3(μ-TTFCO2)]2 (hfac = hexafluoroacetylacetonate).

Keywords: antiferromagnetic exchange gadolinium thiafulvalenecarboxylato fluoroacetylacetonato dinuclear complex; charge transfer spectra gadolinium thiafulvalenecarboxylato fluoroacetylacetonato dinuclear complex; crystal structure gadolinium thiafulvalenecarboxylato fluoroacetylacetonato dinuclear complex; gadolinium thiafulvalenecarboxylato fluoroacetylacetonato dinuclear complex prepn structure; magnetic property gadolinium thiafulvalenecarboxylato fluoroacetylacetonato dinuclear complex

Domains: Chemical Sciences; Organic chemistry

Fabrice Pointillart, Yann Le Gal, Stéphane Golhen, Olivier Cador, Lahcene Ouahab. Binuclear gadolinium(III) coordination complex based on bridging tetrathiafulvalenecarboxylate radical cations.. Chemical Communications, 2009, pp.3777--3779. ⟨10.1039/b901932d⟩. ⟨hal-01151563⟩