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Synthesis of a BEDT-TTF bipyridine organic donor and the first FeII coordination complex with a redox-active ligand.

Katel Hervé 1 Shi-Xia Liu 2 Olivier Cador 3 Stéphane Golhen 3 Yann Le Gal 3 Azzedine Bousseksou 4 Helen Stoeckli-Evans 5 Silvio Decurtins 2 Lahcene Ouahab 3
1 LCSIM - Laboratoire de Chimie du solide et inorganique moléculaire
2 Department of Chemistry and Biochemistry [Bern]
3 ISCR - Institut des Sciences Chimiques de Rennes
4 LCC - Laboratoire de chimie de coordination
5 INSTITUTE OF CHEMISTRY
Abstract : The synthesis of the new ligand, BEDT-TTF-bpy [4,5-ethylenedithio-4',5'-(4'-methyl-2,2'-dipyrid-4- ylethylenedithio)-tetrathiafulvalene] is reported. The first FeII coordination complex, namely [Fe(NCS)2(BEDT-TTF-bpy)2], with this redox-active ligand is obtained. Magnetic measurements and Mossbauer spectroscopy revealed the coexistence of high-spin and low-spin FeII species with a ratio of 40:60 in this compd. The complex also was studied using cyclic voltammetry.
Keywords : antiferromagnetic exchange iron ethylenedithiodipyridylethylenedithio tetrathiafulvalene deriv complex crystal structure dipyridylethylenedithiodithiolone ethylenedithiodipyridylethylenedithio tetrathiafulvalene deriv cyclic voltammetry iron ethylenedithiodipyridylethylenedithio tetrathiafulvalene deriv complex ethylenedithiodipyridylethylenedithio tetrathiafulvalene deriv prepn complexation iron iron ethylenedithiodipyridylethylenedithio tetrathiafulvalene deriv complex prepn Mossbauer effect iron ethylenedithiodipyridylethylenedithio tetrathiafulvalene deriv complex
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01151571
Contributor : Laurent Jonchère <>
Submitted on : Wednesday, May 13, 2015 - 10:22:12 AM
Last modification on : Wednesday, January 13, 2021 - 3:07:53 AM

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UNIV-RENNES1 | SCR_MACSE | ISCR | CNRS | ISCR-OMC | INC-CNRS | UR1-UFR-SPM | UNIV-RENNES | INSA-GROUPE | UNIV-TLSE3 | INSA-RENNES | LCC

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Katel Hervé, Shi-Xia Liu, Olivier Cador, Stéphane Golhen, Yann Le Gal, et al.. Synthesis of a BEDT-TTF bipyridine organic donor and the first FeII coordination complex with a redox-active ligand.. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2006, pp.3498--3502. ⟨10.1002/ejic.200600351⟩. ⟨hal-01151571⟩

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