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Synthesis of a BEDT-TTF bipyridine organic donor and the first FeII coordination complex with a redox-active ligand.

Abstract : The synthesis of the new ligand, BEDT-TTF-bpy [4,5-ethylenedithio-4',5'-(4'-methyl-2,2'-dipyrid-4- ylethylenedithio)-tetrathiafulvalene] is reported. The first FeII coordination complex, namely [Fe(NCS)2(BEDT-TTF-bpy)2], with this redox-active ligand is obtained. Magnetic measurements and Mossbauer spectroscopy revealed the coexistence of high-spin and low-spin FeII species with a ratio of 40:60 in this compd. The complex also was studied using cyclic voltammetry.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01151571
Contributor : Laurent Jonchère <>
Submitted on : Wednesday, May 13, 2015 - 10:22:12 AM
Last modification on : Wednesday, July 15, 2020 - 4:42:36 PM

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Katel Hervé, Shi-Xia Liu, Olivier Cador, Stéphane Golhen, Yann Le Gal, et al.. Synthesis of a BEDT-TTF bipyridine organic donor and the first FeII coordination complex with a redox-active ligand.. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2006, pp.3498--3502. ⟨10.1002/ejic.200600351⟩. ⟨hal-01151571⟩

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