Synthesis of ruthenium N-heterocyclic carbene complexes and their catalytic activity for β-alkylation of tertiary cyclic amines

Ismail Özdemir; Serpil Demir Düşünceli; Nazan Kaloğlu; Mathieu Achard; Christian Bruneau

doi:10.1016/j.jorganchem.2015.10.011

Journal articles

Synthesis of ruthenium N-heterocyclic carbene complexes and their catalytic activity for β-alkylation of tertiary cyclic amines

Ismail Özdemir ¹ Serpil Demir Düşünceli Nazan Kaloğlu Mathieu Achard ² Christian Bruneau ²

1 Inönü University

2 ISCR - Institut des Sciences Chimiques de Rennes

Abstract : The novel ruthenium N-Heterocyclic carbene complexes are synthesized, and characterized by studying its 1H, 13C, elemental analysis, and X-ray. These complexes have been reported as promising catalyst for β C–H bond functionalization of tertiary cyclic amines through hydrogen autotransfers in the presence of external acidic additive. The new catalytic products were characterized by 1H NMR, 13C NMR spectroscopic methods

Keywords : N-Heterocyclic carbene ruthenium Cyclic amine Catalysis

Document type :

Journal articles

Domain :

Chemical Sciences

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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01220885
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Submitted on : Tuesday, October 27, 2015 - 9:46:58 AM
Last modification on : Friday, July 10, 2020 - 4:16:05 PM

Synthesis of ruthenium N-heterocyclic carbene complexes and their catalytic activity for β-alkylation of tertiary cyclic amines

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Synthesis of ruthenium N-heterocyclic carbene complexes and their catalytic activity for β-alkylation of tertiary cyclic amines

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