Synthesis of ruthenium N-heterocyclic carbene complexes and their catalytic activity for β-alkylation of tertiary cyclic amines

İsmail Özdemir (1) , Serpil Demir Düşünceli , Nazan Kaloğlu , Mathieu Achard (2) , Christian Bruneau (2)

1 Inönü University
2 ISCR - Institut des Sciences Chimiques de Rennes

The novel ruthenium N-Heterocyclic carbene complexes are synthesized, and characterized by studying its 1H, 13C, elemental analysis, and X-ray. These complexes have been reported as promising catalyst for β C–H bond functionalization of tertiary cyclic amines through hydrogen autotransfers in the presence of external acidic additive. The new catalytic products were characterized by 1H NMR, 13C NMR spectroscopic methods

Keywords: Catalysis; Cyclic amine; N-Heterocyclic carbene; ruthenium

Domains: Chemical Sciences

İsmail Özdemir, Serpil Demir Düşünceli, Nazan Kaloğlu, Mathieu Achard, Christian Bruneau. Synthesis of ruthenium N-heterocyclic carbene complexes and their catalytic activity for β-alkylation of tertiary cyclic amines. Journal of Organometallic Chemistry, 2015, 799–800, pp.311--315. ⟨10.1016/j.jorganchem.2015.10.011⟩. ⟨hal-01220885⟩