Synthesis of ruthenium N-heterocyclic carbene complexes and their catalytic activity for β-alkylation of tertiary cyclic amines - Archive ouverte HAL Access content directly
Journal Articles Journal of Organometallic Chemistry Year : 2015

Synthesis of ruthenium N-heterocyclic carbene complexes and their catalytic activity for β-alkylation of tertiary cyclic amines

İsmail Özdemir
Serpil Demir Düşünceli
  • Function : Author
Nazan Kaloğlu
  • Function : Author
Mathieu Achard

Abstract

The novel ruthenium N-Heterocyclic carbene complexes are synthesized, and characterized by studying its 1H, 13C, elemental analysis, and X-ray. These complexes have been reported as promising catalyst for β C–H bond functionalization of tertiary cyclic amines through hydrogen autotransfers in the presence of external acidic additive. The new catalytic products were characterized by 1H NMR, 13C NMR spectroscopic methods
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hal-01220885 , version 1 (27-10-2015)

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İsmail Özdemir, Serpil Demir Düşünceli, Nazan Kaloğlu, Mathieu Achard, Christian Bruneau. Synthesis of ruthenium N-heterocyclic carbene complexes and their catalytic activity for β-alkylation of tertiary cyclic amines. Journal of Organometallic Chemistry, 2015, 799–800, pp.311--315. ⟨10.1016/j.jorganchem.2015.10.011⟩. ⟨hal-01220885⟩
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