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Synthesis of ruthenium N-heterocyclic carbene complexes and their catalytic activity for β-alkylation of tertiary cyclic amines

Abstract : The novel ruthenium N-Heterocyclic carbene complexes are synthesized, and characterized by studying its 1H, 13C, elemental analysis, and X-ray. These complexes have been reported as promising catalyst for β C–H bond functionalization of tertiary cyclic amines through hydrogen autotransfers in the presence of external acidic additive. The new catalytic products were characterized by 1H NMR, 13C NMR spectroscopic methods
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01220885
Contributor : Laurent Jonchère <>
Submitted on : Tuesday, October 27, 2015 - 9:46:58 AM
Last modification on : Friday, July 10, 2020 - 4:16:05 PM

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Ismail Özdemir, Serpil Demir Düşünceli, Nazan Kaloğlu, Mathieu Achard, Christian Bruneau. Synthesis of ruthenium N-heterocyclic carbene complexes and their catalytic activity for β-alkylation of tertiary cyclic amines. Journal of Organometallic Chemistry, Elsevier, 2015, 799–800, pp.311--315. ⟨10.1016/j.jorganchem.2015.10.011⟩. ⟨hal-01220885⟩

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