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Journal articles
Mono-N-methylation of anilines with methanol catalyzed by a manganese pincer-complex
Abstract : The selective mono-N-methylation of anilines derivs. was achieved under mild conditions using inexpensive methanol as C1 source. Under hydrogen borrowing conditions, using a tridentate PN3P manganese pre-catalyst (5 mol%), a catalytic amt. of base (20 mol%), for 24 h at 120 °C, a large variety of anilines derivs. was methylated in good to excellent yield. Mechanistic investigations allowed us to isolate and characterize by X-ray diffraction studies a de-aromatized manganese intermediate.
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01475818
Contributor : Laurent Jonchère <>
Submitted on : Friday, February 24, 2017 - 11:07:11 AM
Last modification on : Wednesday, January 13, 2021 - 3:07:47 AM
Contributor : Laurent Jonchère <>
Submitted on : Friday, February 24, 2017 - 11:07:11 AM
Last modification on : Wednesday, January 13, 2021 - 3:07:47 AM