Stabilization of Ni2+ dimers in hexacyano Mo6 cluster-based Prussian blue derivatives: Experimental and theoretical investigations of magnetic properties

G. Daigre (1) , K. Costuas (1) , M.S. Tarasenko (2) , A.Y. Ledneva (2) , N.G. Naumov (3, 2) , P. Lemoine (1) , T. Guizouarn (1) , Y. Molard (1) , M. Amela-Cortes (1) , Nathalie Audebrand (1) , Stéphane Cordier (1)

1 ISCR - Institut des Sciences Chimiques de Rennes
2 Nikolaev Institute of Inorganic Chemistry
3 NSU - Novosibirsk State University

Keywords: Supramolecular Framework; Extended Framework; Single-crystal Structure; Divalent cation; Molybdenum; Ethylenediamine; Clusters compounds; Cyanides

Domains: Chemical Sciences; Material chemistry; Chemical Sciences; Cristallography

G. Daigre, K. Costuas, M.S. Tarasenko, A.Y. Ledneva, N.G. Naumov, et al.. Stabilization of Ni2+ dimers in hexacyano Mo6 cluster-based Prussian blue derivatives: Experimental and theoretical investigations of magnetic properties. Dalton Transactions, 2018, 47 (4), pp.1122-1130. ⟨10.1039/c7dt02748f⟩. ⟨hal-01713505⟩