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Template-Directed Synthesis of a Conjugated Zinc Porphyrin Nanoball

Abstract : We report the template-directed synthesis of a π-conjugated 14-porphyrin nanoball. This structure consists of two intersecting nanorings containing six and 10 porphyrin units. Fluorescence upconversion spectroscopy experiments demonstrate that electronic excitation delocalizes over the whole three-dimensional π system in less than 0.3 ps if the nanoball is bound to its templates or over 2 ps if the nanoball is empty.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01768194
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Submitted on : Friday, April 27, 2018 - 10:26:22 AM
Last modification on : Thursday, March 5, 2020 - 3:24:59 PM

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Jonathan Cremers, Renée Haver, Michel Rickhaus, Juliane Gong, Ludovic Favereau, et al.. Template-Directed Synthesis of a Conjugated Zinc Porphyrin Nanoball. Journal of the American Chemical Society, American Chemical Society, 2018, 140 (16), ⟨10.1021/jacs.8b02552⟩. ⟨hal-01768194v2⟩

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