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Journal articles
Synthesis, crystal structure, catalytic dimerization and S-H insertion of new porphyrin diazoketones
Abstract : Porphyrin diazoketones were synthesized from the corresponding porphyrin acetyl chloride by treatment with trimethylsilyldiazomethane in 60-80% yield. The solid-state structure of one of the two bisdiazo derivatives (trans isomer) was determined by single-crystal X-ray diffraction analysis. Thiol insertion and cis-selectivity in the coupling reactions of porphyrin diazoketones catalyzed by ruthenium porphyrin were observed.
Cited literature [26 references]
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01807081
Contributor : Laurent Jonchère <>
Submitted on : Wednesday, June 20, 2018 - 11:38:22 AM
Last modification on : Thursday, March 5, 2020 - 2:07:27 PM
Contributor : Laurent Jonchère <>
Submitted on : Wednesday, June 20, 2018 - 11:38:22 AM
Last modification on : Thursday, March 5, 2020 - 2:07:27 PM
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Carrié et al_Synthesis, cryst...
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