Directed ortho C-H borylation catalyzed using Cp*Rh(iii)-NHC complexes

Abstract : Cp*Rh(NHC) complexes with bulky chiral bidentate NHC-carboxylate ligands were efficiently synthesized and fully characterized including solid-state structures. These unprecedented rhodium(iii) complexes demonstrated high selectivity in pyridine-directed ortho-C-H borylation of arenes under mild conditions.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01834004
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Submitted on : Tuesday, July 10, 2018 - 10:22:55 AM
Last modification on : Sunday, December 23, 2018 - 7:02:59 PM

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Jompol Thongpaen, Thibault E Schmid, Loic Toupet, Vincent Dorcet, Marc Mauduit, et al.. Directed ortho C-H borylation catalyzed using Cp*Rh(iii)-NHC complexes. Chemical Communications, Royal Society of Chemistry, 2018, 54 (59), pp.8202-8205. ⟨10.1039/c8cc03144d⟩. ⟨hal-01834004⟩

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