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Journal articles
Low-Coordinate Barium Boryloxides: Synthesis and Dehydrocoupling Catalysis for the Production of Borasiloxanes
Abstract : The first soluble barium boryloxides [Ba]–OB{CH(SiMe3)2} are presented. These mono- or dinuclear complexes feature low coordination numbers, as low as two for [Ba(OB{CH(SiMe3)2}2)2], which is further stabilized by intra- and intermolecular Ba···H3C agostic interactions. Ba–boryloxides and the parent [Ba{N(SiMe3)2}2.(thf)2] catalyze the dehydrocoupling of borinic acids with hydrosilanes, providing borasiloxanes under mild conditions.
Cited literature [25 references]
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01862088
Contributor : Yann Sarazin <>
Submitted on : Sunday, August 26, 2018 - 10:10:39 PM
Last modification on : Thursday, March 5, 2020 - 2:07:52 PM
Document(s) archivé(s) le : Tuesday, November 27, 2018 - 12:35:33 PM
Contributor : Yann Sarazin <>
Submitted on : Sunday, August 26, 2018 - 10:10:39 PM
Last modification on : Thursday, March 5, 2020 - 2:07:52 PM
Document(s) archivé(s) le : Tuesday, November 27, 2018 - 12:35:33 PM
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