Heterobimetallic Ba/Li and Ca/Li amides and diphenylmethanide - Archive ouverte HAL Access content directly
Journal Articles Dalton Transactions Year : 2019

Heterobimetallic Ba/Li and Ca/Li amides and diphenylmethanide

(1) , (1) , (1) , (1) , (1) , (1)
1

Abstract

The structures of the heterobimetallic Ca/Li and Ba/Li amides [CaLi2{μ2-N(SiMe2H)2}4]∞ and [Ba2Li2{μ2-N(SiMe2H)2}6]∞, stabilised by metalH-Si interactions, and that of a diphenylmethanide calcium salt, [Li(tmeda)2+·Ca(CHPh2)3(thf)-], are presented. These well-defined, storable compounds are inert towards Et2O and thf.
Fichier principal
Vignette du fichier
Le Coz_et al_Heterobimetallic_accepted.pdf (1.48 Mo) Télécharger le fichier
Origin : Files produced by the author(s)
Loading...

Dates and versions

hal-02120741 , version 1 (05-07-2019)

Identifiers

Cite

Erwann Le Coz, Hanieh Roueindeji, Vincent Dorcet, Thierry Roisnel, Jean-François Carpentier, et al.. Heterobimetallic Ba/Li and Ca/Li amides and diphenylmethanide. Dalton Transactions, 2019, 48 (17), pp.5500-5504. ⟨10.1039/c9dt00771g⟩. ⟨hal-02120741⟩
135 View
278 Download

Altmetric

Share

Gmail Facebook Twitter LinkedIn More