Heterobimetallic Ba/Li and Ca/Li amides and diphenylmethanide

Erwann Le Coz; Hanieh Roueindeji; Vincent Dorcet; Thierry Roisnel; Jean-François Carpentier; Yann Sarazin

Heterobimetallic Ba/Li and Ca/Li amides and diphenylmethanide

Erwann Le Coz ¹ Hanieh Roueindeji ¹ Vincent Dorcet ¹ Thierry Roisnel ¹ Jean-François Carpentier ¹ Yann Sarazin ^{1, *}

* Corresponding author

1 ISCR - Institut des Sciences Chimiques de Rennes

Abstract : The structures of the heterobimetallic Ca/Li and Ba/Li amides [CaLi2{μ2-N(SiMe2H)2}4]∞ and [Ba2Li2{μ2-N(SiMe2H)2}6]∞, stabilised by metalH-Si interactions, and that of a diphenylmethanide calcium salt, [Li(tmeda)2+·Ca(CHPh2)3(thf)-], are presented. These well-defined, storable compounds are inert towards Et2O and thf.

Document type :

Journal articles

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Chemical Sciences

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https://hal-univ-rennes1.archives-ouvertes.fr/hal-02120741
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Submitted on : Friday, July 5, 2019 - 2:19:45 PM
Last modification on : Friday, July 5, 2019 - 4:37:05 PM

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