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Book sections
CHAPTER 4 Secondary (Agostic Si-H/Electrostatic C-F) interactions in alkaline earth-based catalysts
Abstract : The design and implementation of a selection of homogeneous alkaline earth (Ae) catalysts and precatalysts for hydroamination and hydrophosphination of olefins and for ring-opening polymerization of cyclic esters are surveyed. Emphasis is placed on the three large elements calcium, strontium and barium. The role of Ae⋯H–Si and Ae⋯F–C noncovalent interactions in the stabilization of (pre)catalysts is highlighted.
https://hal-univ-rennes1.archives-ouvertes.fr/hal-02122160
Contributor : Laurent Jonchère <>
Submitted on : Tuesday, May 7, 2019 - 10:26:15 AM
Last modification on : Monday, January 27, 2020 - 1:34:45 PM
Contributor : Laurent Jonchère <>
Submitted on : Tuesday, May 7, 2019 - 10:26:15 AM
Last modification on : Monday, January 27, 2020 - 1:34:45 PM