CHAPTER 4 Secondary (Agostic Si-H/Electrostatic C-F) interactions in alkaline earth-based catalysts

Yann Sarazin 1 J.-F. Carpentier 1
1 ISCR - Institut des Sciences Chimiques de Rennes
Abstract : The design and implementation of a selection of homogeneous alkaline earth (Ae) catalysts and precatalysts for hydroamination and hydrophosphination of olefins and for ring-opening polymerization of cyclic esters are surveyed. Emphasis is placed on the three large elements calcium, strontium and barium. The role of Ae⋯H–Si and Ae⋯F–C noncovalent interactions in the stabilization of (pre)catalysts is highlighted.
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Submitted on : Tuesday, May 7, 2019 - 10:26:15 AM
Last modification on : Tuesday, September 10, 2019 - 4:34:40 PM

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UNIV-RENNES1 | ISCR | UR1-UFR-SPM | INC-CNRS | UNIV-RENNES | INSA-GROUPE

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Yann Sarazin, J.-F. Carpentier. CHAPTER 4 Secondary (Agostic Si-H/Electrostatic C-F) interactions in alkaline earth-based catalysts. Noncovalent Interactions in Catalysis, 2019-January (37), Royal Society of Chemistry, pp.94-121, 2019, 9781788017237. ⟨10.1039/9781788016490-00094⟩. ⟨hal-02122160⟩

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