A Comprehensive Spectral Rotational Analysis of the Interstellar Methyl Isocyanate CH3NCO

L. Kolesnikova (1) , Z. Kisiel (2) , E. R. Alonso (1) , J. C. Guillemin (3) , J. L. Alonso (1) , I. R. Medvedev (4) , M. Winnewisser (5)

1 CSIC - Consejo Superior de Investigaciones Cientificas [España] = Spanish National Research Council [Spain]
2 PAN - Polska Akademia Nauk = Polish Academy of Sciences = Académie polonaise des sciences
3 ISCR - Institut des Sciences Chimiques de Rennes
4 Wright State University
5 OSU - Ohio State University [Columbus]

Methyl isocyanate (CH3NCO) is a recently identified interstellar molecule giving rise to many detected lines. Interestingly, its delayed identification was due not to weak lines but to a very complex rotational spectrum. To date, the only published laboratory transitions for this molecule are those between rotational energy levels with K <= 3. In the present work, Stark-modulation spectroscopy was used to record the room-temperature rotational spectrum of CH3NCO in the spectral region from 32 to 90 GHz. Observation of characteristic Stark effects, measured at specific low-voltage modulation conditions, and N-14 nuclear quadrupole hyperfine structure allowed unambiguous assignment of rotational transitions up to K = 10. These newly assigned transitions were subsequently followed up to 364 GHz with the aid of Loomis-Wood-type displays. Since there are no reports on astrophysical detection of C-13 isotopic species, first laboratory measurements between 50 and 300 GHz have also been performed for (CHNCO)-N-3-C-13 and (CH3NCO)-C-13 isotopologues. A comprehensive spectral analysis undertaken in this work made it possible to extend the knowledge of the rotational spectrum of CH3NCO to more than 2500 new transitions. Furthermore, more than 1200 lines were identified and analyzed for each of the isotopologues. The extensive line lists and sets of molecular parameters reported in this work provide the basis for further astrophysical searches of CH3NCO.

Mots clés: Interstellar molecules; Interstellar medium; Spectral line lists; Experimental techniques; Laboratory astrophysics; High resolution spectroscopy; Molecular spectroscopy

Domaines: Chimie

L. Kolesnikova, Z. Kisiel, E. R. Alonso, J. C. Guillemin, J. L. Alonso, et al.. A Comprehensive Spectral Rotational Analysis of the Interstellar Methyl Isocyanate CH3NCO. The Astrophysical Journal Supplement, 2019, 245 (2), ⟨10.3847/1538-4365/ab570d⟩. ⟨hal-02531291⟩