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Gold dithiolene complexes: easy access to 2-alkylthio-thiazoledithiolate complexes

Abstract : In the presence of MeI or EtI, N-tert-butyl-1,3-thiazoline-2-thione derivatives undergo a transformation to 2-alkylthio-thiazoledithiolate pro-ligands with elimination of the tert-butyl substituent. The corresponding Au(III) dithiolene complexes [Au(RS-tzdt)2](-) (R = Me, Et) oxidize readily to the neutral radical species, such as the semi-conducting [Au(EtS-tzdt)2]˙, which organizes into dimers in the solid state.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01188234
Contributor : Laurent Jonchère <>
Submitted on : Friday, August 28, 2015 - 4:26:06 PM
Last modification on : Wednesday, October 14, 2020 - 4:04:49 AM

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Agathe Filatre-Furcate, Pascale Auban-Senzier, Marc Fourmigué, Thierry Roisnel, Vincent Dorcet, et al.. Gold dithiolene complexes: easy access to 2-alkylthio-thiazoledithiolate complexes. Dalton Transactions, Royal Society of Chemistry, 2015, 44 (35), pp.15683--15689. ⟨10.1039/C5DT02534F⟩. ⟨hal-01188234⟩

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