How the Anchoring Site on Two Extended Tetrathiafulvalenes Impacts the Electronic Communication through a Bis(acetylide)ruthenium Linker

Hadi Hachem 1 Antoine Vacher 1 Vincent Dorcet 1 Dominique Lorcy 1
1 ISCR - Institut des Sciences Chimiques de Rennes
Abstract : The interplay between two extended tetrathiafulvalenes connected, from either the dithiole rings or the anthraquinodimethane moieties, through a bis(acetylide) ruthenium linker has been studied within the novel complexes trans-[Ru(C CDTTFAQ)(2)(dppe)(2)] and trans-[Ru(C CATTFAQ)(2)(dppe)(2)]. Cyclic voltammetry and spectroelectrochemical investigations show that the organic and inorganic electrophores are electronically coupled within these complexes. Moreover, the electronic. communication between the two organic electrophores depends on the localization of the anchoring site of the organometallic bis(acetylide) ruthenium linker on the organic electrophores.
Type de document :
Article dans une revue
Organometallics, American Chemical Society, 2017, 36 (11), pp.2208-2217. 〈10.1021/acs.organomet.7b00257〉
Liste complète des métadonnées
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01559206
Contributeur : Laurent Jonchère <>
Soumis le : mercredi 13 septembre 2017 - 15:41:08
Dernière modification le : vendredi 16 novembre 2018 - 01:35:24
Document(s) archivé(s) le : jeudi 14 décembre 2017 - 14:12:02

Fichiers

PubliDLorcy Organometallics.pd...
Fichiers produits par l'(les) auteur(s)

Identifiants

Collections

ISCR | ISCR-PRATS | SCR_MACSE | INC-CNRS | UR1-UFR-SPM | UNIV-RENNES | SCR-MI-INSA | INSA-RENNES

Citation

Hadi Hachem, Antoine Vacher, Vincent Dorcet, Dominique Lorcy. How the Anchoring Site on Two Extended Tetrathiafulvalenes Impacts the Electronic Communication through a Bis(acetylide)ruthenium Linker. Organometallics, American Chemical Society, 2017, 36 (11), pp.2208-2217. 〈10.1021/acs.organomet.7b00257〉. 〈hal-01559206〉

Exporter

BibTeX TEI DC DCterms EndNote

Partager

Métriques

Consultations de la notice

107

Téléchargements de fichiers

25