Asymmetric synthesis of hetero-1,2,3,4,5-pentasubstituted ferrocenes

Abstract : The first synthesis of enantioenriched ferrocenes bearing five different substituents on the same cyclopentadienyl ring is described through unprecedented asymmetric halogen 'dance'. Not only this work extends the chemistry of fluoroferrocene derivatives and constitutes the very first entry into the world of enantioenriched hetero-pentasubstituted ferrocenes, it also lays the ground for researches in other metallocene families.
Document type :
Journal articles
Complete list of metadatas

Cited literature [15 references]  Display  Hide  Download

https://hal-univ-rennes1.archives-ouvertes.fr/hal-02278407
Contributor : Laurent Jonchère <>
Submitted on : Monday, November 18, 2019 - 10:17:17 AM
Last modification on : Tuesday, November 19, 2019 - 9:50:57 AM

Files

 Restricted access
To satisfy the distribution rights of the publisher, the document is embargoed until : 2020-01-04

Please log in to resquest access to the document

Identifiers

Citation

William Erb, Thierry Roisnel. Asymmetric synthesis of hetero-1,2,3,4,5-pentasubstituted ferrocenes. Chemical Communications, Royal Society of Chemistry, 2019, 55 (62), pp.9132-9135. ⟨10.1039/c9cc04604f⟩. ⟨hal-02278407⟩

Share

Metrics

Record views

14